Issue 27, 2021
From the journal:

Dalton Transactions

Cation-translocation based isomerism offers a tool for the expansion of compressed helicates†

Christian Mevissen,a   David Sommer, ORCID logo a   Sabarina Vasanthakumar,a   Khai-Nghi Truong, ORCID logo b   Kari Rissanen ORCID logo b  and  Markus Albrecht ORCID logo *a  

* Corresponding authors

a Institut für Organische Chemie, RWTH Aachen University, Landoltweg 1, 52074 Aachen, Germany
E-mail: markus.albrecht@oc.rwth-aachen.de

b University of Jyvaskyla, Department of Chemistry, P.O. Box 35, Survontie 9 B, 40014 Jyväskylä, Finland

Abstract

A series of compressed M[Li313Ti2] (M = Li, Na, K, Rb, Cs) and expanded helicates M4[13Ti2] has been obtained. The helicates Li3[M13Ti2] or M4[13Ti2] with M = Na+, K+, Rb+, or Cs+ adopt the expanded structure in solution. By crystallization the compressed structures M[Li313Ti2] (M = Na, Rb) are obtained. This represents an example of cation-translocation based isomerism.

Graphical abstract: Cation-translocation based isomerism offers a tool for the expansion of compressed helicates

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/D1DT01707A
Article type
Communication
Submitted
26 May 2021
Accepted
07 Jun 2021
First published
09 Jun 2021

Dalton Trans., 2021,50, 9372-9375

Permissions

Request permissions

Cation-translocation based isomerism offers a tool for the expansion of compressed helicates

C. Mevissen, D. Sommer, S. Vasanthakumar, K. Truong, K. Rissanen and M. Albrecht, Dalton Trans., 2021, 50, 9372 DOI: 10.1039/D1DT01707A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements