We disclose a synthetic route that providess an unprecedented library of C1 salan ligands endowed with (N–H) backbones, previously limited to N-methylated backbones. Efforts to identify a generic complexation protocol to yield the corresponding Cu(II)–salan complexes demonstrate the scope and limitations of this approach.
J. Devonport, J. Spencer and G. E. Kostakis, Dalton Trans., 2021, 50, 12069 DOI: 10.1039/D1DT01950C
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