Accessing the triplet manifold of naphthalene benzimidazole–phenanthroline in rhenium(i) bichromophores

Abstract

The steady-state and ultrafast to supra-nanosecond excited state dynamics of fac-[Re(NBI-phen)(CO)₃(L)](PF₆) (NBI-phen = 16H-benzo[4′,5′]isoquinolino[2′,1′:1,2]imidazo[4,5-f][1,10]phenanthrolin-16-one) as well as their respective models of the general molecular formula [Re(phen)(CO)₃(L)](PF₆) (L = PPh₃ and CH₃CN) has been investigated using transient absorption and time-gated photoluminescence spectroscopy. The NBI-phen containing molecules exhibited enhanced visible light absorption with respect to their models and a rapid formation (<6 ns) of the triplet ligand-centred (LC) excited state of the organic ligand, NBI-phen. These triplet states exhibit an extended excited state lifetime that enable the energized molecules to readily engage in triplet–triplet annihilation photochemistry.