Size controlled silver nanoparticles on β-cyclodextrin/graphitic carbon nitride: an excellent nanohybrid material for SERS and catalytic applications

Abstract

A nanohybrid (NH), having high dispersion of silver nanoparticles (AgNPs) on β-cyclodextrin (β-CD)/graphitic carbon nitride (g-CN), designated as AgNPs/β-CD/g-CN-NH, was synthesized and characterized. It was exploited for a couple of environmental remediation applications like SERS sensing and catalytic reduction of specific organic pollutants in water. It showed excellent SERS activity as a Raman probe for the detection of malachite green (MG). Its enhancement factor (EF) and detection limit for MG were equal to 7.26 × 10⁶ and 1 × 10⁻⁹ M, respectively. The relative standard deviation (RSD) was equal to 3.8% which indicates high homogeneity of AgNP dispersion and signal reproducibility of the SERS substrate. The NH displayed high catalytic activity for the reduction of eosin yellow (EY) in the presence of NaBH₄ with the rate constant (k) of 0.1142 min⁻¹. A comparison of the present NH with other reported materials reveals better SERS and catalytic activities of the former than those of the latter. The SERS activity of the NH was also examined for sensing of other triphenylamine dyes like methyl violet (MV), and it was successful. The same NH also exhibited high catalytic activity towards the reduction of Congo red (CR). The results of both studies clarify that the NH is an excellent SERS substrate and efficient catalyst for the detection of organic environmental pollutants having structures similar to MG and their degradation. This is due to the distribution of the controlled size of AgNPs on g-CN promoted by β-CD. Therefore, we focus our attention on future environmental applications of the nanohybrid as a very cheap SERS substrate and a very active catalyst.