A pillar-layered chalcogenide framework assembled by [Mn5S12N12]n layers and [Sb2S5] inorganic pillars

Peipei Sun; Jin Wu; Zhiqiang Wang; Xiang Wang; Ning Chen; Tao Wu

doi:10.1039/D1DT02838C

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A pillar-layered chalcogenide framework assembled by [Mn₅S₁₂N₁₂]_n layers and [Sb₂S₅] inorganic pillars†

Peipei Sun,^a Jin Wu,

^a Zhiqiang Wang,^a Xiang Wang,

^a Ning Chen

^a and Tao Wu

*^b

Author affiliations

* Corresponding authors

^a College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, Jiangsu 215123, China

^b College of Chemistry and Materials Science, Guangdong Provincial Key Laboratory of Functional Supramolecular Coordination Materials and Applications, Jinan University, Guangzhou, Guangdong 510632, China
E-mail: wutao@jnu.edu.cn

Abstract

Reported here is an attractive pillar-layered metal chalcogenide open framework, in which [Sb₂S₅] building units act as pillars between [Mn₅S₁₂(N₂H₄)₆]_n layers. The obtained compound exhibits high stability in both acid and base media and good performance in the electrocatalytic oxygen reduction reaction (ORR).

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Article information

DOI: https://doi.org/10.1039/D1DT02838C
Article type: Communication
Submitted: 24 Aug 2021
Accepted: 18 Oct 2021
First published: 18 Oct 2021

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Dalton Trans., 2021,50, 16473-16477

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A pillar-layered chalcogenide framework assembled by [Mn₅S₁₂N₁₂]_n layers and [Sb₂S₅] inorganic pillars

P. Sun, J. Wu, Z. Wang, X. Wang, N. Chen and T. Wu, Dalton Trans., 2021, 50, 16473 DOI: 10.1039/D1DT02838C

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