Synthesis and optical properties of N→Ga coordinated gallium boroxines

Abstract

Reactions of the N,C,N-chelated organogallium amide LGa(NEt₂)₂ (1), where L is {2,6-(Me₂NCH₂)₂C₆H₃}⁻, with organoboronic acids RB(OH)₂ yielded molecular gallium boroxines LGa(O₃B₂R₂) (2: R = OH, 3: R = Ph, 4: R = 4-MeO–C₆H₄, 5: R = 4-CHO–C₆H₄, 6: R = Fc), neutral analogues of gallaborates. The molecular structures revealed the presence of a six-membered central GaB₂O₃ ring. The film forming properties of 5 allowed the deposition of transparent thin films by a spin coating method. The thicknesses, refractive index, energy of the optical gap (E^opt_g), activation energy of surface electrical conductivity (E^s_a) and pre-exponential factor (σ₀) of the thin layers of 5 were measured and they are close to those found for related oxygen glass. Finally, GBO 5 was also used as an additive to printing ink and a thin film of 5 was prepared by the gravure printing technique.