Amorphous NiCoB-coupled MAPbI3 for efficient photocatalytic hydrogen evolution

Abstract

It was thought that the organic–inorganic hybrid perovskite MAPbI₃ could be used to collect visible light for the photocatalytic hydrogen evolution reaction (HER). However, its ability to generate H₂ is limited. Herein, we synthesized amorphous NiCoB through a redox method and coupled it with MAPbI₃ to form the NiCoB/MAPbI₃ composite photocatalyst by electrostatic self-assembly. 30% NiCoB/MAPbI₃ exhibited the maximum H₂ generation yield of 2625.57 μmol g⁻¹ h⁻¹, which was approximately 114 fold that of pristine MAPbI₃ and much better than that of Pt/MAPbI₃. In addition to the excellent photocatalytic HER capability, NiCoB/MAPbI₃ maintained good stability in the 24 h cycling hydrogen evolution experiment. The photoelectric analysis showed that NiCoB as a cocatalyst could realize rapid charge separation. This work can offer a reference for the construction of efficient photocatalysts based on lead halide perovskites.