Preparation and characterization of Pd supported on 5-carboxyoxindole functionalized cell@Fe3O4 nanoparticles as a novel magnetic catalyst for the Heck reaction

Abstract

Pd supported on 5-carboxyoxindole functionalized cell@Fe₃O₄ nanoparticles (Pd@CAI@cell@Fe₃O₄), a new magnetic nanocatalyst, was prepared and characterized using inductively coupled plasma atomic emission spectroscopy, Fourier-transform infrared spectroscopy, X-ray diffraction, scanning electron microscopy, transmission electron microscopy, thermogravimetric analysis, and energy-dispersive X-ray spectroscopy techniques. The synthesized nanocatalyst (Pd@CAI@cell@Fe₃O₄) was employed for Heck-type arylation of different substituted maleimides with iodoarenes in good to excellent yields. This green catalyst was easily recovered and reused several times with no substantial loss of activity, providing a clean and efficient synthetic procedure with excellent yield and reduced time.