Issue 35, 2021

Visible light driven selective NADH regeneration using a system of water-soluble zinc porphyrin and homogeneous polymer-dispersed rhodium nanoparticles

Abstract

We discovered the catalytic activity of Rh nanoparticles dispersed by polyvinylpyrrolidone (Rh–PVP) for NADH regeneration. The selective reduction of NAD+ to enzyme active NADH has successfully been achieved in the presence of an electron donor, ZnTPPS as a photosensitizer, and Rh–PVP. Only 1,4-NADH was produced as the reduction product of NAD+, which was validated by an enzymatic assay and HPLC.

Graphical abstract: Visible light driven selective NADH regeneration using a system of water-soluble zinc porphyrin and homogeneous polymer-dispersed rhodium nanoparticles

Supplementary files

Article information

Article type
Communication
Submitted
10 Jun 2021
Accepted
17 Aug 2021
First published
18 Aug 2021

New J. Chem., 2021,45, 15748-15752

Visible light driven selective NADH regeneration using a system of water-soluble zinc porphyrin and homogeneous polymer-dispersed rhodium nanoparticles

T. Katagiri and Y. Amao, New J. Chem., 2021, 45, 15748 DOI: 10.1039/D1NJ02856A

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