A review of Mn-based catalysts for low-temperature NH3-SCR: NOx removal and H2O/SO2 resistance

Abstract

The development of high-efficiency catalysts is the key to the low-temperature NH₃-SCR technology. The introduction of SO₂ and H₂O will lead to poisoning and deactivation of the catalysts, which severely limits the development and application of NH₃-SCR technology. This review introduces the necessity of NO_x removal, explains the mechanisms of H₂O and SO₂ poisoning on NH₃-SCR catalysts, highlights the Mn-based catalysts of different active metals and supports and their resistance to H₂O and SO₂, and analyses the relationship between metal modification, selection of support and preparation method, morphology and structure design and SO₂/H₂O resistance. Given the current problems, this review points out the future research focus of Mn-based catalysts and also puts forward corresponding countermeasures to solve the existing problems.