This review will cover the importance of and most recent approaches toward geminal difluoroalkyl groups. Transition metal-mediated, photochemical, organocatalytic, and other methods as well as their mechanistic implications will be discussed, with special emphasis on applications to biologically-relevant compounds.
D. R. Carvalho and A. H. Christian, Org. Biomol. Chem., 2021, 19, 947 DOI: 10.1039/D0OB02374D
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