Regioselective C(sp3)–H alkylation of a fructopyranose derivative using electron-deficient alkenes as alkylation reagents was achieved. The reaction proceeded via 1,6-hydrogen atom transfer under photoredox iridium catalysis. Several functional groups were introduced into the fructopyranose derivative.
Y. Li, S. Miyamoto, T. Torigoe and Y. Kuninobu, Org. Biomol. Chem., 2021, 19, 3124 DOI: 10.1039/D1OB00326G
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