Issue 2, 2021

Electrochemical tandem trifluoromethylation of allylamines/formal (3 + 2)-cycloaddition for the rapid access to CF3-containing imidazolines and oxazolidines

Abstract

An electrochemical tandem radical trifluoromethylation of allylamines/formal (3 + 2)-cycloaddition with nitrile and carbonyl compounds has been developed under mild and environmentally benign reaction conditions. Such multicomponent reaction allowed the construction of CF3-containing imidazolines and oxazolidines by creating three new bonds from simple and easily available starting materials.

Graphical abstract: Electrochemical tandem trifluoromethylation of allylamines/formal (3 + 2)-cycloaddition for the rapid access to CF3-containing imidazolines and oxazolidines

Supplementary files

Article information

Article type
Research Article
Submitted
23 Oct 2020
Accepted
23 Nov 2020
First published
24 Nov 2020

Org. Chem. Front., 2021,8, 288-296

Electrochemical tandem trifluoromethylation of allylamines/formal (3 + 2)-cycloaddition for the rapid access to CF3-containing imidazolines and oxazolidines

A. Claraz, A. Djian and G. Masson, Org. Chem. Front., 2021, 8, 288 DOI: 10.1039/D0QO01307B

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