Pillar[5]arene-based ion-pair recognition for constructing a [2]pseudorotaxane with supramolecular interaction induced LCST behavior

Ming Li; Bin Hua; Feihe Huang

doi:10.1039/D1QO00457C

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Pillar[5]arene-based ion-pair recognition for constructing a [2]pseudorotaxane with supramolecular interaction induced LCST behavior†

Ming Li,

^a Bin Hua

*^ab and Feihe Huang

*^abc

Author affiliations

* Corresponding authors

^a State Key Laboratory of Chemical Engineering, Key Laboratory of Excited-State Materials of Zhejiang Province, Stoddart Institute of Molecular Science, Department of Chemistry, Zhejiang University, Hangzhou 310027, China
E-mail: huabin@zju.edu.cn, fhuang@zju.edu.cn
Fax: +86-571-8795-3189
Tel: +86-571-8795-3189

^b ZJU-Hangzhou Global Scientific and Technological Innovation Center, Hangzhou, China

^c Green Catalysis Center and College of Chemistry, Zhengzhou University, Zhengzhou 450001, China

Abstract

A LCST-type [2]pseudorotaxane based on perbromoethylated pillar[5]arene/imidazolium iodide ionic liquid ion-pair recognition is constructed in both solution and the solid state. The thermo-responsive behavior can be adjusted by altering the molar ratio of the host and guest as well as the concentrations of these two components in solution.

This article is part of the themed collections: FOCUS: Macrocyclic and supramolecular chemistry and Macrocycle-based Supramolecular Elements

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Article information

DOI: https://doi.org/10.1039/D1QO00457C
Article type: Research Article
Submitted: 23 Mar 2021
Accepted: 04 May 2021
First published: 10 May 2021

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Org. Chem. Front., 2021,8, 3675-3680

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Pillar[5]arene-based ion-pair recognition for constructing a [2]pseudorotaxane with supramolecular interaction induced LCST behavior

M. Li, B. Hua and F. Huang, Org. Chem. Front., 2021, 8, 3675 DOI: 10.1039/D1QO00457C

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Organic Chemistry Frontiers

Pillar[5]arene-based ion-pair recognition for constructing a [2]pseudorotaxane with supramolecular interaction induced LCST behavior†

Abstract

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Pillar[5]arene-based ion-pair recognition for constructing a [2]pseudorotaxane with supramolecular interaction induced LCST behavior

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