Iron oxide coated hollow poly(methylmethacrylate) as an efficient adsorption media for removal of arsenic from water

Abstract

Adsorption of arsenic onto iron-based adsorption media has been established as a convenient method for the removal of arsenic from contaminated water. The study describes the efficiency of iron oxide coated hollow poly(methyl methacrylate) microspheres (FHM) as an adsorptive media for the removal of arsenic from water. Hollow poly(methyl methacrylate) microspheres (HPMM) were synthesized by solvent evaporation and an electroless plating technique and the surface of the polymer was coated with iron oxide (FeO) particles. Structural characterization was performed using Optical Microscopy (OM), Scanning Electron Microscopy (SEM), Fourier Transform Infrared spectroscopy (FTIR), Energy Dispersive X-ray diffraction (EDAX), and Thermogravimetric Analysis (TGA). A study on the effect of the varying initial concentration of arsenic ions on percentage removal was performed in the laboratory and the adsorption capacity of the adsorbent was measured. Adsorption isotherm studies were carried out to evaluate the adsorption efficiency of FHM in removing arsenic from contaminated water. The Langmuir and Freundlich isotherm models were used to analyze the equilibrium experimental data. The isotherm study revealed that Langmuir adsorption data are well fitted and the maximum adsorption capacity of FHM in removing arsenic is 10.031 mg g⁻¹. This high arsenic uptake capability combined with a low density of FHM makes it a potential material for arsenic removal particularly during the fabrication of lightweight portable water purification devices.