Design of a novel poly(aryl ether nitrile)-based composite ultrafiltration membrane with improved permeability and antifouling performance using zwitterionic modified nano-silica

Abstract

Zwitterionic nano-silica (SiO₂ NPs) obtained by lysine surface modification was used as a hydrophilic inorganic filler for preparing a poly(aryl ether nitrile) (PEN) nanocomposite membrane via an immersion precipitation phase inversion method. The effects of zwitterionic SiO₂ NPs addition on the morphology, separation and antifouling performance of the synthesized membranes were investigated. Zwitterionic surface modification effectively avoided the agglomeration of SiO₂ NPs. The PEN/zwitterionic SiO₂ NPs composite membranes exhibited improved porosity, equilibrium water content, hydrophilicity and permeability due to the introduction of hydrophilic SiO₂ NPs in the casting solution, and the optimal pure water flux was up to 507.2 L m⁻² h⁻¹, while the BSA rejection ratio was maintained at 97.4%. A static adsorption capacity of 72.9 μg cm⁻² and the FRR up to 85.3% in the dynamic antifouling experiment proved that the introduction of zwitterionic SiO₂ NPs inhibited irreversible fouling and enhanced the antifouling ability of the PEN membrane.