Investigation of kinetics and adsorption isotherm for fluoride removal from aqueous solutions using mesoporous cerium–aluminum binary oxide nanomaterials

Abstract

Herein, we report the synthesis of Ce–Al (1 : 1, 1 : 3, 1 : 6, and 1 : 9) binary oxide nanoparticles by a simple co-precipitation method at room temperature to be applied for defluoridation of an aqueous solution. The characterization of the synthesized nanomaterial was performed by XRD (X-ray diffraction), FTIR (Fourier transform infrared) spectroscopy, TGA/DTA (thermogravimetric analysis/differential thermal analysis), BET (Brunauer–Emmett–Teller) surface analysis, and SEM (scanning electron microscopy). Ce–Al binary oxides in 1 : 6 molar concentration were found to have the highest surface area of 110.32 m² g⁻¹ with an average crystallite size of 4.7 nm, which showed excellent defluoridation capacity. The adsorptive capacity of the prepared material towards fluoride removal was investigated under a range of experimental conditions such as dosage of adsorbents, pH, and initial fluoride concentration along with adsorption isotherms and adsorption kinetics. The results indicated that fluoride adsorption on cerium–aluminum binary metal oxide nanoparticles occurred within one hour, with maximum adsorption occurring at pH 2.4. The experimental data obtained were studied using Langmuir, Freundlich, and Temkin adsorption isotherm models. The nanomaterial showed an exceptionally high adsorbent capacity of 384.6 mg g⁻¹. Time-dependent kinetic studies were carried out to establish the mechanism of the adsorption process by pseudo-first-order kinetics, pseudo-second-order kinetics, and Weber–Morris intraparticle diffusion kinetic models. The results indicated that adsorption processes followed pseudo-second-order kinetics. This study suggests that cerium–aluminum binary oxide nanoparticles have good potential for fluoride removal from highly contaminated aqueous solutions.