Synergy ascension of SnS/MoS2 binary metal sulfides on initial coulombic efficiency and stable capacity for lithium storage

Abstract

Numerous efforts have been devoted to capability improvement and cycling stability in the past decades, and these performances have been significantly enhanced. Low initial coulombic efficiency is still a problem in the metal sulfide-based anode materials. This study developed a strategy to achieve high initial coulombic efficiency and superior capacity retention by interpenetrating binary metal sulfides of SnS and MoS₂ in a conductive carbon matrix. The synergy ascension of electrochemical performances for the metal sulfides is attributed to their mutual impeding effects on coarsening of metal grains and the capsule-shaped coating structure embedded in the carbon sheet architecture. The SnS/MoS₂/C composite was prepared by a simple NaCl template-assisted ball milling method, and showed excellent electrochemical performances in terms of a high initial coulombic efficiency up to 90.2% and highly stable reversibility with a specific capacity of 515.4 mA h g⁻¹ after 300 cycles at 1.0 A g⁻¹. All of these characteristics suggest that the proposed materials are superior among the previously reported metal sulfide-based anode materials for lithium-ion batteries.