Tunable LSPR of silver/gold bimetallic nanoframes and their SERS activity for methyl red detection

Abstract

Ag/Au bimetallic nanostructures have received much attention in surface-enhanced Raman scattering (SERS). However, the synthesis of this nanostructure type still remains a challenge. In the present research, Ag/Au nanoframes were synthesized via a simple room temperature solution phase chemical reduction method using pre-synthesized triangular Ag nanoplates as templates in the presence of appropriate amounts of HAuCl₄. Controlling experimental parameters was applied for understanding of the growth mechanism. The galvanic exchange reaction resulted in a uniform deposition of the Au shell on the Ag nanoplates and the Ag core was removed which generated triangular hollow nanoframes. It is found that the amount of HAuCl₄ added to the growth solution played a key role in controlling the Ag/Au nanoframes. The resultant silver/gold nanoframes with average size of 50 nm were applied in detecting methyl red (MR) in the solution-phase using an excitation wavelength laser of 532 nm. The SERS signal was greatly enhanced owing to the tunable plasmonic peaks in the visible region (400–650 nm). The limit of detection (LOD) of MR in diluted solution was 10⁻⁶ M. The enhancement factor (EF) was about 8 × 10⁴ toward 10⁻⁵ M of MR. Interestingly, the linear dependence between the logarithm of the SERS signal intensity (log I) and the logarithm of the MR concentration (log C) occurred in the range from 10⁻⁶ to 10⁻⁴ M. Our work promises the application of Ag/Au nanoframes as a chemical sensor in detecting MR molecules at low concentration with high performance.