A novel 3D terbium metal–organic framework as a heterogeneous Lewis acid catalyst for the cyanosilylation of aldehyde

Abstract

A novel 3D lanthanide(III) metal–organic framework (MOF) (namely Tb-MOF), was synthesized by self-assembly from Tb(III) ion nitrate and the rigid organic ligand H₂sbdc (H₂sbdc = 5,5-dioxo-5H-dibenzo[b,d]thiophene-3,7-dicarboxylic acid), and could work as an efficient heterogeneous catalyst for the cyanosilylation of aromatic aldehydes at room temperature. The obtained Tb-MOF has been characterized and analysed in detail by single crystal X-ray diffraction, powder X-ray diffraction, thermogravimetric analysis and so on. The pores of Tb-MOF provided a microenvironment that was beneficial for the substrates to be close to the Lewis acid catalytic sites. The IR spectrogram and the fluorescence titration proved that the substrates could be activated inside the channel of Tb-MOF. The heterogeneous Tb-MOF catalyst with fine catalytic efficiency exhibited a high TON (TON = 460), and could be recycled at least three times without significantly reducing its activity.