Structural evolution and dielectric properties of biaxially oriented polyethylene/multiwalled carbon nanotube composite films

Abstract

In modern power systems, polymer nanocomposite films have been more frequently used as dielectric materials for capacitors. However, the low energy storage density limits its application in more areas. It is a very challenging task to prepare dielectric films with high dielectric constant (ε), high energy storage density, and low dielectric loss (tan δ) at the same time. In this study, one kind of BOPE (biaxially oriented polyethylene) nanocomposite dielectric films with a very small amount of MWCNTs (multiwalled carbon nanotubes) was reported. MWCNTs with a high aspect ratio were used for conductive filler, and the formation of more micro capacitors and interfacial polarization were caused by better dispersibility of MWCNTs in polyethylene matrix by biaxial stretching. The BOPE/MWCNT composite films with high-performance were successfully prepared by achieving the requirements of low content, high dielectric constant and high energy storage density while maintaining the advantages of low dielectric loss of the polymer matrix. The dielectric constant of the BOPE/MWCNT composite films increased from 2.26 to 4.68 with the drawing ratio was 4 × 4 and the content of MWCNTs was 0.6 wt% and the energy storage density was also increased from 1.01 J cm⁻³ to 1.29 J cm⁻³. From our work, the achievement of low thickness, high energy density and low loss at the same time implied BOPE/MWCNT composite films were promising materials for next-generation film capacitors.