Issue 31, 2021

Temperature stable Sm(Nb1−xVx)O4 (0.0 ≤ x ≤ 0.9) microwave dielectric ceramics with ultra-low dielectric loss for dielectric resonator antenna applications

Abstract

Herein, the structure and dielectric properties of Sm(Nb1−xVx)O4 (SNV-x) (0.0 ≤ x ≤ 0.9) ceramics were studied by crystal structure refinement, Raman, transmission electron microscope (TEM), far-infrared/THz reflectivity spectroscopy and microwave dielectric tests. Three kinds of ultra-low dielectric loss and temperature-stable Sm(Nb1−xVx)O4 (0.2 ≤ x ≤ 0.4) ceramics with permittivities of 18.01–16.89, Q × f values of 97 800–75 200 GHz (@∼8.6 GHz), and TCF of −5.6 (x = 0.2), to +2.3 ppm °C−1 (x = 0.3), then −6.3 (x = 0.4) ppm °C−1 were synthesized in this system. It was found that V5+ substitution can reliably induce the phase transition of monoclinic fergusonite (M-fergusonite, I2/a) to tetragonal zircon phase (T-zircon, I41/amd) (x ≈ 0.3), while effectively reducing the phase transition temperature. TEM shows that there were two different orientation domain structures in the M-fergusonite phase, and the widths of the two domain structures get closer with an increase in B-site substitution. Moreover, the variations in permittivity (εr), quality factor (Q × f), and the temperature coefficient of resonance frequency (TCF) were strongly related to the crystal distortion and phase transition. Notably, a rectangular dielectric resonator antenna (RDRA) was fabricated with an Sm(Nb0.8V0.2)O4 (SNV-0.2) specimen. The antenna resonated at 27.04 GHz and had a bandwidth of ∼820 MHz (S11 < −10 dB). This system is a good candidate for 5G and future millimeter-wave applications.

Graphical abstract: Temperature stable Sm(Nb1−xVx)O4 (0.0 ≤ x ≤ 0.9) microwave dielectric ceramics with ultra-low dielectric loss for dielectric resonator antenna applications

Supplementary files

Article information

Article type
Paper
Submitted
24 May 2021
Accepted
30 Jun 2021
First published
05 Jul 2021

J. Mater. Chem. C, 2021,9, 9962-9971

Temperature stable Sm(Nb1−xVx)O4 (0.0 ≤ x ≤ 0.9) microwave dielectric ceramics with ultra-low dielectric loss for dielectric resonator antenna applications

F. Wu, D. Zhou, C. Du, S. Sun, L. Pang, B. Jin, Z. Qi, J. Varghese, Q. Li and X. Zhang, J. Mater. Chem. C, 2021, 9, 9962 DOI: 10.1039/D1TC02390J

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