A gel fluorescence sensor based on CDs@SiO2/FeS2@MIPs for the visual detection of p-chlorophenol

Abstract

There is a critical need for the rapid detection of p-chlorophenol produced by pesticide abuse and industrial wastewater discharge, which has been an urgent problem in the realm of environmental protection. Here, a green and environmentally friendly method was developed to prepare stable and low toxicity quantum dots. First, blue-green fluorescent FeS₂ quantum dots (B-FeS₂ QDs) were prepared with FeCl₃·6H₂O (an iron source) and L-cysteine (a capping agent) by the solvothermal method. By combining B-FeS₂ QDs with orange carbon dots (O-CDs), a CDs@SiO₂/FeS₂@MIPs visual fluorescence sensor for the selective detection of p-chlorophenol was constructed. Under optimum conditions, this sensor exhibited a detection limit of 1.265 μM with a linear range of 5.00–50.00 μM and was successfully applied to detect p-chlorophenol in real samples. Moreover, this sensor was successfully applied to visual semi-quantitative detection of p-chlorophenol. This work demonstrated that these sensors, based on FeS₂ QDs and CDs, had potentials for in situ and visual detection of environmental contaminants.