Issue 2, 2022

Ligand-controlled cobalt-catalyzed remote hydroboration and alkene isomerization of allylic siloxanes

Abstract

The Co-catalyzed remote hydroboration and alkene isomerization of allylic siloxanes were realized by a ligand-controlled strategy. The remote hydroboration with dcype provided borylethers, while xantphos favored the formation of silyl enol ethers.

Graphical abstract: Ligand-controlled cobalt-catalyzed remote hydroboration and alkene isomerization of allylic siloxanes

Supplementary files

Article information

Article type
Communication
Submitted
25 Oct 2021
Accepted
01 Dec 2021
First published
02 Dec 2021

Chem. Commun., 2022,58, 302-305

Ligand-controlled cobalt-catalyzed remote hydroboration and alkene isomerization of allylic siloxanes

P. Zhao, J. Huang, J. Li, K. Zhang, W. Yang and W. Zhao, Chem. Commun., 2022, 58, 302 DOI: 10.1039/D1CC05964E

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements