Au(I)-mediated N2-elimination from triazaphospholes: a one-pot synthesis of novel N2P2-heterocycles

Erlin Yue; Lea Dettling; Julian A. W. Sklorz; Selina Kaiser; Manuela Weber; Christian Müller

doi:10.1039/D1CC06205K

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Au(i)-mediated N₂-elimination from triazaphospholes: a one-pot synthesis of novel N₂P₂-heterocycles†

Erlin Yue,

‡^ab Lea Dettling,

‡^a Julian A. W. Sklorz,^a Selina Kaiser,^a Manuela Weber^a and Christian Müller

*^a

Author affiliations

* Corresponding authors

^a Freie Universität Berlin, Institute of Chemistry and Biochemistry, Fabeckstr. 34/36, Berlin 14195, Germany
E-mail: c.mueller@fu-berlin.de, yueerlin@yau.edu.cn

^b Shaanxi Key Laboratory of Chemical Reaction Engineering, Key Laboratory of New Energy & New Functional Materials, College of Chemistry and Chemical Engineering, Yan’an University, Yan’an, Shaanxi 716000, People's Republic of China

Abstract

Novel tosyl- and mesitylsulfonyl-substituted triazaphospholes were synthesized and structurally characterized. In an attempt to prepare the corresponding Au(I)-complexes with stoichiometric amounts of AuCl·S(CH₃)₂, cyclo-1,3-diphospha(III)-2,4-diazane-AuCl-complexes were obtained instead. Our here presented results offer a new strategy for preparing such coordination compounds selectively in a one-pot approach.

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Article information

DOI: https://doi.org/10.1039/D1CC06205K
Article type: Communication
Submitted: 03 Nov 2021
Accepted: 29 Nov 2021
First published: 29 Nov 2021
This article is Open Access

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Chem. Commun., 2022,58, 310-313

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Au(I)-mediated N₂-elimination from triazaphospholes: a one-pot synthesis of novel N₂P₂-heterocycles

E. Yue, L. Dettling, J. A. W. Sklorz, S. Kaiser, M. Weber and C. Müller, Chem. Commun., 2022, 58, 310 DOI: 10.1039/D1CC06205K

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