Synthesis of polyantimony ligand complexes starting from Cp*4Sb4

Abstract

The reactivity of Cp*₄Sb₄ (1) towards ionic compounds and transition metal complexes with labile ligands was investigated in order to synthesize polyantimony ligand complexes. The silver salts [Ag][X] and the metalate Na[Cp*Mo(CO)₃] were primarily used, leading in the raction with Cp*₄Sb₄ to the formation of [Cp*₂Sb][X] (X = TEF (2a), FAL (2b)), [(Cp*Mo(CO)₃)₃(μ₃-Sb₃)] (3) and [Cp*Mo(CO)₂(η³-Sb₃)] (4), respectively. The reaction of 1 with the transition metal complexes [(Cp′′′M)₂(tol)] leads to a degradation of the original Sb₄ unit and to the formation of [(Cp′′′M)₄(μ₃-Sb)₄] (M = Ni (5); Co (6)). Towards [Cp^RFe(CO)₂]₂, substitutions on the antimony atoms were observed to give [{Cp^RFe(CO)₂}₄(μ₄-Sb₄)] (Cp^R = Cp′′ (7a), Cp′′′ (7b)). All complexes were characterized by XRD and spectroscopic methods.