Fluorinated tris(pyrazolyl)borate supporting ligands enable the stabilization of silver(I) bonded to a neutral, organometallic Fe(CO)5 ligand. The Ag–Fe interaction in these molecules is mainly electrostatic in nature, but σ-donor and backbonding contributions between the two metal fragments also play notable roles, which can be modulated by the scorpionate substituents.
G. Wang, A. Noonikara-Poyil, I. Fernández and H. V. R. Dias, Chem. Commun., 2022, 58, 3222 DOI: 10.1039/D1CC06859H
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