Issue 27, 2022
From the journal:

Chemical Communications

Orthogonal reactivity and interface-driven selectivity during cation exchange of heterostructured metal sulfide nanorods†

Abigail M. Fagan, ORCID logo ‡a   Benjamin C. Steimle ORCID logo ‡a  and  Raymond E. Schaak ORCID logo *abc  

* Corresponding authors

a Department of Chemistry, The Pennsylvania State University, University Park, PA, USA
E-mail: res20@psu.edu

b Department of Chemical Engineering, The Pennsylvania State University, University Park, PA, USA

c Materials Research Institute, The Pennsylvania State University, University Park, PA, USA

Abstract

We report predictive guidelines for the substoichiometric cation exchange of model two-component metal sulfide nanorods containing divalent cations of similar hardness. Unit cell volume changes, cation radii, solubility constants, and solid state interfaces influence selectivity during substoichiometric exchange of Cu+ when multiple products are possible.

Graphical abstract: Orthogonal reactivity and interface-driven selectivity during cation exchange of heterostructured metal sulfide nanorods

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Article information

DOI
https://doi.org/10.1039/D1CC07190D
Article type
Communication
Submitted
23 Dec 2021
Accepted
03 Mar 2022
First published
03 Mar 2022

Chem. Commun., 2022,58, 4328-4331

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Orthogonal reactivity and interface-driven selectivity during cation exchange of heterostructured metal sulfide nanorods

A. M. Fagan, B. C. Steimle and R. E. Schaak, Chem. Commun., 2022, 58, 4328 DOI: 10.1039/D1CC07190D

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