Issue 26, 2022

Serendipitous formation of oxygen-bridged Cu II6M (M = MnII, CoII) double cubanes showing electrocatalytic water oxidation

Abstract

Hydroxido-bridged CuII6M double-cubane clusters (M = MnII, CoII) supported by D-penicillaminedisulfide were unexpectedly formed by treating a D-penicillaminato CuII2PtII2 complex with MBr2 in water. The clusters displayed heterogeneous electrocatalytic activities for water oxidation dependent on the central M shared by two CuII cubane units.

Graphical abstract: Serendipitous formation of oxygen-bridged CuII6M (M = MnII, CoII) double cubanes showing electrocatalytic water oxidation

Supplementary files

Article information

Article type
Communication
Submitted
23 Dec 2021
Accepted
04 Mar 2022
First published
07 Mar 2022

Chem. Commun., 2022,58, 4192-4195

Serendipitous formation of oxygen-bridged CuII6M (M = MnII, CoII) double cubanes showing electrocatalytic water oxidation

A. C. M. San Esteban, N. Kuwamura, N. Yoshinari and T. Konno, Chem. Commun., 2022, 58, 4192 DOI: 10.1039/D1CC07199H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements