Issue 30, 2022
From the journal:

Chemical Communications

Transition structures for the oxy–ene reaction†

Shengwen Yang,ab   Solène Miaskiewicz,a   Christophe Bour, ORCID logo a   Aurélien Alixa  and  Vincent Gandon ORCID logo *ab  

* Corresponding authors

a Université Paris-Saclay, CNRS, Institut de Chimie Moléculaire et des Matériaux d'Orsay, 91405, Orsay, France
E-mail: vincent.gandon@universite-paris-saclay.fr

b Laboratoire de Chimie Moléculaire (LCM), CNRS UMR 9168, Ecole Polytechnique, Institut Polytechnique de Paris, Route de Saclay, 91128 Palaiseau cedex, France

Abstract

An overlooked pericyclic reaction between allyl alcohols and alkenes to form carbonyl compounds is analyzed. It combines the characteristic features of the Alder–ene reaction and of the oxy-Cope rearrangement. This oxy–ene reaction could be involved in biosynthetic pathways.

Graphical abstract: Transition structures for the oxy–ene reaction

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Article information

DOI
https://doi.org/10.1039/D2CC00687A
Article type
Communication
Submitted
03 Feb 2022
Accepted
21 Mar 2022
First published
21 Mar 2022
This article is Open Access
Creative Commons BY license

Chem. Commun., 2022,58, 4751-4754

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Transition structures for the oxy–ene reaction

S. Yang, S. Miaskiewicz, C. Bour, A. Alix and V. Gandon, Chem. Commun., 2022, 58, 4751 DOI: 10.1039/D2CC00687A

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