Selective carbon-phosphorus bond cleavage: expanding the toolbox for accessing bulky divalent lanthanoid sandwich complexes

Angus C. G. Shephard; Daisy P. Daniels; Glen B. Deacon; Zhifang Guo; Florian Jaroschik; Peter C. Junk

doi:10.1039/D2CC00698G

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Selective carbon-phosphorus bond cleavage: expanding the toolbox for accessing bulky divalent lanthanoid sandwich complexes†

Angus C. G. Shephard,^a Daisy P. Daniels,^b Glen B. Deacon,

^b Zhifang Guo,^a Florian Jaroschik*^c and Peter C. Junk

*^a

Author affiliations

* Corresponding authors

^a College of Science & Engineering, James Cook University, Townsville, QLD, Australia
E-mail: peter.junk@jcu.edu.au

^b School of Chemistry, Monash University, Clayton, VIC, Australia

^c ICGM, Univ Montpellier, CNRS, ENSCM, Montpellier, France

Abstract

The synthesis of two new tetra- and penta-phenycyclopentadienyldiphenylphosphine pro-ligands which readily undergo selective C–P bond cleavage has allowed for the facile synthesis of bulky divalent octa- and deca-phenylmetallocenes of europium, ytterbium and samarium.

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Article information

DOI: https://doi.org/10.1039/D2CC00698G
Article type: Communication
Submitted: 04 Feb 2022
Accepted: 09 Mar 2022
First published: 09 Mar 2022

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Chem. Commun., 2022,58, 4344-4347

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Selective carbon-phosphorus bond cleavage: expanding the toolbox for accessing bulky divalent lanthanoid sandwich complexes

A. C. G. Shephard, D. P. Daniels, G. B. Deacon, Z. Guo, F. Jaroschik and P. C. Junk, Chem. Commun., 2022, 58, 4344 DOI: 10.1039/D2CC00698G

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Chemical Communications

Selective carbon-phosphorus bond cleavage: expanding the toolbox for accessing bulky divalent lanthanoid sandwich complexes†

Abstract

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Selective carbon-phosphorus bond cleavage: expanding the toolbox for accessing bulky divalent lanthanoid sandwich complexes

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