Issue 52, 2022
From the journal:

Chemical Communications

Fabricating defect-rich metal–organic frameworks via mixed linker-induced crystal transformation†

Yue Xiao, ORCID logo a   Lu Han,a   Jihai Tang, ORCID logo a   Lifang Tian, ORCID logo b   Zhuxiu Zhang,*a   Lixiong Zhang,*a   Dong Yang*a  and  Xu Qiaoa  

* Corresponding authors

a State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemical Engineering, Nanjing Tech University, Nanjing 211816, China
E-mail: zhuxiu.zhang@njtech.edu.cn, dyang@njtech.edu.cn

b Institute of Advanced Synthesis (IAS), School of Chemistry and Molecular Engineering, Nanjing Tech University, Nanjing 211816, China

Abstract

Defect-rich hcp UiO-66-NO2 was synthesized via mixed linker-induced crystal transformation from fcu UiO-66-NO2/NH2. The defect concentration and porosity of hcp UiO-66-NO2 can be fine-tuned by varying the BDC-NH2/BDC-NO2 ratio, which in turn endowed hcp UiO-66-NO2 with superior catalytic performance in the ring-opening reaction of epoxides with alcohols.

Graphical abstract: Fabricating defect-rich metal–organic frameworks via mixed linker-induced crystal transformation

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Article information

DOI
https://doi.org/10.1039/D2CC00923D
Article type
Communication
Submitted
14 Feb 2022
Accepted
27 May 2022
First published
01 Jun 2022

Chem. Commun., 2022,58, 7265-7268

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Fabricating defect-rich metal–organic frameworks via mixed linker-induced crystal transformation

Y. Xiao, L. Han, J. Tang, L. Tian, Z. Zhang, L. Zhang, D. Yang and X. Qiao, Chem. Commun., 2022, 58, 7265 DOI: 10.1039/D2CC00923D

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