Issue 54, 2022
From the journal:

Chemical Communications

Sign control of circularly polarized luminescence of chiral Schiff-base Zn(ii) complexes through coordination geometry changes†

Masahiro Ikeshita, ORCID logo *a   Momo Mizugaki,a   Takahiro Ishikawa,a   Kana Matsudaira,b   Maho Kitahara,b   Yoshitane Imai ORCID logo *b  and  Takashi Tsuno ORCID logo *a  

* Corresponding authors

a Department of Applied Molecular Chemistry, College of Industrial Technology, Nihon University, Narashino, Chiba 275-8575, Japan
E-mail: ikeshita.masahiro@nihon-u.ac.jp, tsuno.takashi@nihon-u.ac.jp

b Department of Applied Chemistry, Faculty of Science and Engineering, Kindai University, 3-4-1 Kowakae, Higashi-Osaka, Osaka 577-8502, Japan
E-mail: y-imai@apch.kindai.ac.jp

Abstract

The handedness of circularly polarized luminescence (CPL) of Zn(II) complexes with a chiral Schiff-base ligand can be controlled by coordination geometry changes in solution and in the solid state. The relationships between molecular structure and chiroptical properties were discussed with the results of X-ray diffraction analysis and DFT calculations.

Graphical abstract: Sign control of circularly polarized luminescence of chiral Schiff-base Zn(ii) complexes through coordination geometry changes

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Article information

DOI
https://doi.org/10.1039/D2CC01959K
Article type
Communication
Submitted
06 Apr 2022
Accepted
01 Jun 2022
First published
03 Jun 2022

Chem. Commun., 2022,58, 7503-7506

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Sign control of circularly polarized luminescence of chiral Schiff-base Zn(II) complexes through coordination geometry changes

M. Ikeshita, M. Mizugaki, T. Ishikawa, K. Matsudaira, M. Kitahara, Y. Imai and T. Tsuno, Chem. Commun., 2022, 58, 7503 DOI: 10.1039/D2CC01959K

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