Deep eutectic solvents coupled with (NH4)3H6CoMo6O24 trigger aerobic oxidation of 5-hydroxymethylfurfural to 5-formyl-2-furancarboxylic acid

Yanbin Sun; Kaixuan Yang; Zhiguo Zhu; Ting Su; Wanzhong Ren; Hongying Lü

doi:10.1039/D2CC02544B

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Deep eutectic solvents coupled with (NH₄)₃H₆CoMo₆O₂₄ trigger aerobic oxidation of 5-hydroxymethylfurfural to 5-formyl-2-furancarboxylic acid†

Yanbin Sun,^a Kaixuan Yang,^a Zhiguo Zhu,

^a Ting Su,

^a Wanzhong Ren^a and Hongying Lü

*^a

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* Corresponding authors

^a College of Chemistry and Chemical Engineering, Yantai University, Yantai, Shandong, China
E-mail: hylv@ytu.edu.cn

Abstract

An Anderson-type polyoxometalate (NH₄)₃H₆CoMo₆O₂₄ in deep eutectic solvents exhibited outstanding catalytic performance for the selective aerobic oxidation of HMF to FFCA. It is potentially a promising and highly environmentally friendly approach for biomass conversion.

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Article information

DOI: https://doi.org/10.1039/D2CC02544B
Article type: Communication
Submitted: 05 May 2022
Accepted: 24 Jun 2022
First published: 25 Jun 2022

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Chem. Commun., 2022,58, 8105-8108

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Deep eutectic solvents coupled with (NH₄)₃H₆CoMo₆O₂₄ trigger aerobic oxidation of 5-hydroxymethylfurfural to 5-formyl-2-furancarboxylic acid

Y. Sun, K. Yang, Z. Zhu, T. Su, W. Ren and H. Lü, Chem. Commun., 2022, 58, 8105 DOI: 10.1039/D2CC02544B

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Chemical Communications