The importance of crystal size for breathing kinetics in MIL-53(Al)

Volodymyr Bon; Nikita Busov; Irena Senkovska; Nadine Bönisch; Leila Abylgazina; Azat Khadiev; Dmitri Novikov; Stefan Kaskel

doi:10.1039/D2CC02662G

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

The importance of crystal size for breathing kinetics in MIL-53(Al)†

Volodymyr Bon,

*^a Nikita Busov,‡^a Irena Senkovska,

^a Nadine Bönisch,^a Leila Abylgazina,^a Azat Khadiev,^b Dmitri Novikov^b and Stefan Kaskel

*^a

Author affiliations

* Corresponding authors

^a Chair of Inorganic Chemistry I, Technische Universität Dresden, Bergstraße 66, 01069 Dresden, Germany
E-mail: volodymyr.bon@tu-dresden.de, stefan.kaskel@tu-dresden.de

^b P23 group, Petra III Synchrotron, DESY, Notkestraße 85, 22607, Hamburg, Germany

Abstract

Herein we analyze the switching kinetics of a breathing framework MIL-53(Al) with respect to different crystallite size regimes. Synchrotron time-resolved powder X-ray diffraction (PXRD) and adsorption rate analysis of n-butane physisorption at 298 K demonstrate the decisive role of crystal size affecting the time domain of breathing transitions in MIL-53(Al).

This article is part of the themed collection: Celebrating 10 years of ChemComm Emerging Investigators

Download options Please wait...

Supplementary files

Supplementary information PDF (2466K)

Article information

DOI: https://doi.org/10.1039/D2CC02662G
Article type: Communication
Submitted: 10 May 2022
Accepted: 29 Jul 2022
First published: 22 Aug 2022

Download Citation

Chem. Commun., 2022,58, 10492-10495

Permissions

Request permissions

The importance of crystal size for breathing kinetics in MIL-53(Al)

V. Bon, N. Busov, I. Senkovska, N. Bönisch, L. Abylgazina, A. Khadiev, D. Novikov and S. Kaskel, Chem. Commun., 2022, 58, 10492 DOI: 10.1039/D2CC02662G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications

The importance of crystal size for breathing kinetics in MIL-53(Al)†

Abstract

Supplementary files

Article information

Download Citation

Permissions

The importance of crystal size for breathing kinetics in MIL-53(Al)

Social activity

Search articles by author

Spotlight

Advertisements