Complete twin suppression in oriented NH2-MIL-125 film via facile coordination modulation

Yanwei Sun; Liangliang Liu; Taotao Ji; Jiahui Yan; Yi Liu

doi:10.1039/D2CC03028D

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Complete twin suppression in oriented NH₂-MIL-125 film via facile coordination modulation†

Yanwei Sun,^a Liangliang Liu,^a Taotao Ji,^a Jiahui Yan^a and Yi Liu

*^ab

Author affiliations

* Corresponding authors

^a State Key Laboratory of Fine Chemicals, School of Chemical Engineering Dalian University of Technology Dalian, China
E-mail: diligenliu@dlut.edu.cn

^b Dalian Key Laboratory of Membrane Materials and Membrane Processes Dalian University of Technology Dalian, China

Abstract

Complete suppression of twin crystal formation in oriented metal–organic framework (MOF) film remains a great challenge. In this study, we successfully avoided the twin generation in c-oriented NH₂-MIL-125 film through simple competitive metal ion-based coordination modulation. Simultaneously, relevant mechanism associated with twin suppression was elucidated.

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Article information

DOI: https://doi.org/10.1039/D2CC03028D
Article type: Communication
Submitted: 28 May 2022
Accepted: 11 Jul 2022
First published: 12 Jul 2022

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Chem. Commun., 2022,58, 8822-8825

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Complete twin suppression in oriented NH₂-MIL-125 film via facile coordination modulation

Y. Sun, L. Liu, T. Ji, J. Yan and Y. Liu, Chem. Commun., 2022, 58, 8822 DOI: 10.1039/D2CC03028D

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Chemical Communications