Dynamic covalent chemistry has become an invaluable tool for the design and preparation of adaptable yet robust molecular systems. Herein we explore the scope of a largely overlooked dynamic covalent reaction – amidinium exchange – and report on conditions that allow formal amidinium metathesis reactions.
O. Borodin, Y. Shchukin, J. Schmid and M. von Delius, Chem. Commun., 2022, 58, 10178 DOI: 10.1039/D2CC03425E
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