Site-selective photoredox reactions with aromatic olefins enable direct alkylation of unprotected myo-inositol at C4. The efficacy of these reactions can be finely tuned by modifying the structures of HAT reagents. These reactions open the possibility of selective C–H alkylations of myo-inositol without the need for multi-step protection–deprotection strategies.
H. Cao, T. Guo, X. Deng, X. Huo, S. Tang, J. Liu and X. Wang, Chem. Commun., 2022, 58, 9934 DOI: 10.1039/D2CC03569C
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