Dy3+ single ion magnet in the extended inorganic solid Ca(Y,Dy)AlO4

Pavel E. Kazin; Mikhail A. Zykin; Andrey K. Dyakonov; Alexander V. Vasiliev; Maxim A. Karpov; Evgeny A. Gorbachev; Anastasia E. Sleptsova; Martin Jansen

doi:10.1039/D2CC03668A

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Dy³⁺ single ion magnet in the extended inorganic solid Ca(Y,Dy)AlO₄†

Pavel E. Kazin,

*^a Mikhail A. Zykin,

^a Andrey K. Dyakonov,^a Alexander V. Vasiliev,^a Maxim A. Karpov,^a Evgeny A. Gorbachev,^b Anastasia E. Sleptsova^b and Martin Jansen

Author affiliations

* Corresponding authors

^a Department of Chemistry, Lomonosov Moscow State University, Moscow 119991, Russia
E-mail: kazin@inorg.chem.msu.ru
Tel: +7 495 9393440

^b Department of Materials Science, Lomonosov Moscow State University, Moscow 119991, Russia

^c Max Planck Institute for Solid State Research, Heisenbergstrasse 1, Stuttgart 70569, Germany

Abstract

The first instance of a rare-earth single-ion magnet in a robust extended solid has been found, which possesses a crystal structure different from apatite. The compound exhibits slow relaxation of magnetization in a zero field revealing simultaneously two energy barriers for magnetization reversal.

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Article information

DOI: https://doi.org/10.1039/D2CC03668A
Article type: Communication
Submitted: 01 Jul 2022
Accepted: 19 Oct 2022
First published: 20 Oct 2022

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Chem. Commun., 2022,58, 12572-12575

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Dy³⁺ single ion magnet in the extended inorganic solid Ca(Y,Dy)AlO₄

P. E. Kazin, M. A. Zykin, A. K. Dyakonov, A. V. Vasiliev, M. A. Karpov, E. A. Gorbachev, A. E. Sleptsova and M. Jansen, Chem. Commun., 2022, 58, 12572 DOI: 10.1039/D2CC03668A

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