Issue 76, 2022

Diverse reactivity of a magnesium silanide toward ketones

Abstract

The reactivity of a molecular magnesium silanide toward ketones displays a significant variability of outcome, resulting in adduct formation, deprotonation, dearomatisation or deoxygenation, that is dependent on the structure and electronic character of the carbonyl-containing reagent.

Graphical abstract: Diverse reactivity of a magnesium silanide toward ketones

Supplementary files

Article information

Article type
Communication
Submitted
15 Jul 2022
Accepted
30 Aug 2022
First published
30 Aug 2022
This article is Open Access
Creative Commons BY license

Chem. Commun., 2022,58, 10711-10714

Diverse reactivity of a magnesium silanide toward ketones

B. Okokhere-Edeghoghon, M. S. Hill, M. F. Mahon and C. L. McMullin, Chem. Commun., 2022, 58, 10711 DOI: 10.1039/D2CC03966D

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