Herein, we report two 2,2′-pyridylpyrrolide (PyPyrH) ligand supported magnesium complexes (1 and 2), which demonstrate bright luminescence with a quantum yield of 22% and 14% in the solid state, respectively. Theoretical calculations reveal that their emissive properties originate from the intra- and inter-ligand charge transfer.
R. Kumar, S. Pahar, J. Chatterjee, S. R. Dash, R. G. Gonnade, K. Vanka and S. S. Sen, Chem. Commun., 2022, 58, 11843 DOI: 10.1039/D2CC04142A
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