Micropatterning of electrochemiluminescent polymers based on multipolar Ru-complex two-photon initiators

Rana Mhanna; Nicolas Durand; Paul Savel; Huriye Akdas-Kiliç; Stephania Abdallah; Davy-Louis Versace; Olivier Soppera; Jean-Luc Fillaut; Neso Sojic; Jean-Pierre Malval

doi:10.1039/D2CC04159F

Micropatterning of electrochemiluminescent polymers based on multipolar Ru-complex two-photon initiators†

Rana Mhanna,^a Nicolas Durand,^b Paul Savel,^b Huriye Akdas-Kiliç,^bc Stephania Abdallah,

^a Davy-Louis Versace,

^d Olivier Soppera,

^a Jean-Luc Fillaut,^b Neso Sojic

^e and Jean-Pierre Malval

*^a

Author affiliations

* Corresponding authors

^a Institut de Science des Matériaux de Mulhouse CNRS-UMR 7361, Université de Haute Alsace, Mulhouse, France
E-mail: jean-pierre.malval@uha.fr

^b Université de Rennes, Institut des Sciences Chimiques de Rennes CNRS UMR, Rennes, France

^c Yildiz Technical University, Department of Chemistry, Istanbul, Turkey

^d Institut de Chimie et des Matériaux Paris-Est, UMR-CNRS 7182, Université Paris-Est Créteil, Thiais, France

^e Université de Bordeaux, Institut des Sciences Moléculaires, UMR 5255 CNRS, Talence, France

Abstract

In this work, we present an original stereolithography strategy based on multibranched Ru-complexes with a high two-photon initiating ability allowing the ‘one-pot’ direct laser writing of ECL-active materials deposited onto electro-active surfaces at the μm scale.

Chemical Communications

Micropatterning of electrochemiluminescent polymers based on multipolar Ru-complex two-photon initiators†

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Micropatterning of electrochemiluminescent polymers based on multipolar Ru-complex two-photon initiators

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