Issue 95, 2022
From the journal:

Chemical Communications

Electronic properties of lithium-ion conductive amorphous lithium phosphorus oxynitride†

Futa Nakayama,a   Yasuhiro Suzuki,a   Keisuke Yoshikawa,a   Satoshi Yamamoto,a   Miyuki Sakakura,a   Tsuyoshi Ohnishib  and  Yasutoshi Iriyama ORCID logo *a  

* Corresponding authors

a Department of Materials Design Engineering, Graduate School of engineering, Nagoya University, Furo-cho, Chikusa-ku, Nagoya, Aichi, Japan
E-mail: iriyama.yasutoshi@material.nagoya-u.ac.jp

b Center for Green Research on Energy and Environmental Materials, National Institute for Materials Science (NIMS), 1-1 Namiki, Tsukuba, Ibaraki, Japan

Abstract

The valence band maxima of Li+ conductive amorphous lithium phosphorus oxynitride (LiPON) electrolyte depend on the chemical bonding states, and isolated nonbonding oxygen raises them. In contrast, the conduction band minima of the LiPON are independent of the composition and the values are less than the work function of Li.

Graphical abstract: Electronic properties of lithium-ion conductive amorphous lithium phosphorus oxynitride

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Article information

DOI
https://doi.org/10.1039/D2CC05117F
Article type
Communication
Submitted
16 Sep 2022
Accepted
07 Nov 2022
First published
11 Nov 2022

Chem. Commun., 2022,58, 13262-13265

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Electronic properties of lithium-ion conductive amorphous lithium phosphorus oxynitride

F. Nakayama, Y. Suzuki, K. Yoshikawa, S. Yamamoto, M. Sakakura, T. Ohnishi and Y. Iriyama, Chem. Commun., 2022, 58, 13262 DOI: 10.1039/D2CC05117F

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