Issue 95, 2022

Electronic, steric and catalytic properties of N-heterocyclic carbene rhodium(i) complexes linked to (metallo)porphyrins

Abstract

Electronic and steric properties of NHC ligands functionalized with porphyrins were investigated. When porphyrins are used as NHC-wingtips, nickel(II) in the macrocyle significantly improves the catalytic activity of the neighbouring NHC-Rh(I) complex in the conjugate addition of phenylboronic acid to cyclohexen-2-one.

Graphical abstract: Electronic, steric and catalytic properties of N-heterocyclic carbene rhodium(i) complexes linked to (metallo)porphyrins

Supplementary files

Article information

Article type
Communication
Submitted
11 Oct 2022
Accepted
05 Nov 2022
First published
07 Nov 2022
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2022,58, 13270-13273

Electronic, steric and catalytic properties of N-heterocyclic carbene rhodium(I) complexes linked to (metallo)porphyrins

L. Poyac, S. Scoditti, X. Dumail, M. Granier, S. Clément, R. Gramage-Doria, C. H. Devillers and S. Richeter, Chem. Commun., 2022, 58, 13270 DOI: 10.1039/D2CC05547C

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