Methyl vinyl glycolate (MVG) can be obtained by acid-catalyzed conversion of C4 and C6 sugars. Applications of MVG in polymers are so far limited to its use as co-monomer for poly(lactic acid) and as crosslinking agent. In this work, hydroformylation and methoxycarbonylation of MVG were investigated to produce novel bifunctional monomers. Polyesters with high renewable-atom content were successfully prepared and characterized.
A. Dell’Acqua, C. Schünemann, E. Baráth, S. Tin and J. G. de Vries, Chem. Commun., 2022, 58, 13091 DOI: 10.1039/D2CC05609G
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