Fine-tuning of the ratio of two different states is important in controlling the structures and functions of crystalline materials. Here we report that clathrated guest molecules inside a tubular host crystal formed via halogen and hydrogen bonding exhibit reversible temperature-dependent orientational isomerisation in equilibrium.
Y. Yamashita, S. Tashiro and M. Shionoya, CrystEngComm, 2022, 24, 1518 DOI: 10.1039/D1CE01654G
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