[Ru(N∧N∧N)2-Ce]-based framework for photocatalytic sulfide oxidation and hydrogen production

Yong-Hui Yu; Sheng-Li Huang; Guo-Yu Yang

doi:10.1039/D2CE00397J

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[Ru(N^∧N^∧N)₂-Ce]-based framework for photocatalytic sulfide oxidation and hydrogen production†

Yong-Hui Yu,^a Sheng-Li Huang

*^a and Guo-Yu Yang*^a

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* Corresponding authors

^a MOE Key Laboratory of Cluster Science, School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing 100081, P. R. China
E-mail: huangsl@bit.edu.cn, ygy@bit.edu.cn

Abstract

Using the photosensitized Ru(N^∧N^∧N)₂-metalloligand, a series of Ce frameworks were synthesized. The incorporation of the visible-light-responsive Ru(N^∧N^∧N)₂-unit endows the Ce frameworks with photocatalytic activities in both sulfide oxidation and hydrogen production. The doping of Zr and particularly the oxidation state of Ce has great influence on the photocatalytic properties of the Ce frameworks.

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Article information

DOI: https://doi.org/10.1039/D2CE00397J
Article type: Communication
Submitted: 21 Mar 2022
Accepted: 04 Apr 2022
First published: 12 Apr 2022

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CrystEngComm, 2022,24, 3160-3164

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[Ru(N^∧N^∧N)₂-Ce]-based framework for photocatalytic sulfide oxidation and hydrogen production

Y. Yu, S. Huang and G. Yang, CrystEngComm, 2022, 24, 3160 DOI: 10.1039/D2CE00397J

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