Issue 4, 2022
From the journal:

Physical Chemistry Chemical Physics

Oxidative evolution of Z/E-diaminotetraphenylethylene†

Xin Li,a   Yongbing Zhuang, ORCID logo b   Qichao Ran ORCID logo *a  and  Xiangyang Liu ORCID logo *a  

* Corresponding authors

a College of Polymer Science and Engineering, State Key Laboratory of Polymer Material and Engineering, Sichuan University, Chengdu 610065, P. R. China

b State Key Laboratory of Biochemical Engineering, Institute of Process Engineering, University of Chinese Academy of Sciences, Chinese Academy of Sciences, Beijing 100190, P. R. China

Abstract

We report that Z/E-diaminotetraphenylethylene (Z/E-2NH2-TPE) molecules suffer primarily from oxidative evolution rather than recognized isomerization. The oxide is separated and its structure is deciphered by single crystal X-ray diffraction. The oxidative evolution accompanying the rearrangement is explained through quantum theoretical calculation.

Graphical abstract: Oxidative evolution of Z/E-diaminotetraphenylethylene

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Article information

DOI
https://doi.org/10.1039/D1CP05303E
Article type
Communication
Submitted
19 Nov 2021
Accepted
05 Jan 2022
First published
07 Jan 2022

Phys. Chem. Chem. Phys., 2022,24, 1960-1964

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Oxidative evolution of Z/E-diaminotetraphenylethylene

X. Li, Y. Zhuang, Q. Ran and X. Liu, Phys. Chem. Chem. Phys., 2022, 24, 1960 DOI: 10.1039/D1CP05303E

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