Issue 2, 2022

Hybrid organic–inorganic triguanidine arsenate dihydrate for ultraviolet nonlinear optical application

Abstract

Introduction of the planar organic cation [C(NH2)3]+ into tetrahedronal inorganic arsenate generates a new ultraviolet nonlinear optical crystal triguanidine arsenate dihydrate, [C(NH2)3]3AsO4·2H2O, which exhibits a short ultraviolet absorption edge (210 nm), suitable second-harmonic generation response (0.9 × KDP), and moderate birefringene (0.0387 at 546 nm). Notably, by optimizing the growth conditions, transparent and wafer well-developed bulk single crystals can be easily prepared.

Graphical abstract: Hybrid organic–inorganic triguanidine arsenate dihydrate for ultraviolet nonlinear optical application

Supplementary files

Article information

Article type
Communication
Submitted
30 Sep 2021
Accepted
06 Dec 2021
First published
15 Dec 2021

Dalton Trans., 2022,51, 463-467

Hybrid organic–inorganic triguanidine arsenate dihydrate for ultraviolet nonlinear optical application

D. Wang, Z. Wei, Z. Bai, L. Liu, Z. Lin and L. Zhang, Dalton Trans., 2022, 51, 463 DOI: 10.1039/D1DT03323A

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