Unusual motion of the n-methoxypropyl moiety observed in the photochromic crystals of an organorhodium dithionite complex with n-methoxypropyltetramethylcyclopentadienyl ligands

Abstract

The crystalline-state photochromism of a new organorhodium dinuclear complex having n-methoxypropyltetramethylcyclopentadienyl (η⁵-C₅Me₄n-C₃H₆OCH₃) and photoresponsive dithionite (μ-O₂SSO₂) ligands was investigated directly by performing single-crystal X-ray diffraction experiments; a reversible conformational change of the n-methoxypropyl moiety was intriguingly observed during the course of a thermal back-reaction.